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Nontargeted pattern recognition in the search for pyrolysis gas chromatography/mass spectrometry resin markers in historic lacquered objects

Research output: Contribution to journalA1: Web of Science-articlepeer-review

  • Louise Decq
  • Emmanuel Abatih
  • Henk Van Keulen
  • Viviane Leyman
  • Vincent Cattersel
  • Delphine Steyaert
  • Emile Van Binnebeke
  • Wim Fremout
  • Steven Saverwyns
  • Frederic Lynen
A differential expression analysis technology developed for linear modeling of gene expression data was used in combination with thermally assisted hydrolysis and methylation gas chromatography/mass spectrometry (THM-GC/MS) to support the analysis of lacquers and varnishes on historical objects. Exudates from tropical trees, such as Manila copal, sandarac, South American copal, and Congo copal, which were frequently used in finishing layers on decorative objects up to the early 20th century, were compared through this approach. Highly discriminating features indicate biomarkers that can help to identify copals in resinous lacquers. The approach allows new, more systematic ways for finding biomarkers in the analysis of lacquered objects of art and varnishes.
Original languageEnglish
JournalAnalytical Chemistry
Volume91
Issue number11
Pages (from-to)7131-7138
Number of pages8
ISSN0003-2700
Publication statusPublished - 2019

    Research areas

  • MASS-SPECTROMETRY, NATURAL RESINS, COPAL, IDENTIFICATION, METABOLOMICS, DISCOVERY, VARNISHES, WESTERN, AMBER
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